Presuming it's basically the same as my old Murano, it's intrinsically a FWD vehicle, with a drive shaft running rearwards from the transmission to the rear diff with an electromagnet activated clutch pack. Only at low speeds, flip that switch and it locks the magnet on, otherwise it only activates if the VDC system detects slip.
And btw, that clutch pack is NOT the same as locking a 4x4 into 4hi. Effectively it's similar, but it's not strong enough to send 100% of the engine power to the rear wheels, only 50% tops, and the rear diff is undersized accordingly as well. It's a driving in snow or getting unstuck from the muddy parking lot kinda system, don't expect to keep going too well if you have a wheel in the air

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That being said, at least on the Murano the AWD version had a MUCH better driving feel. Less nose-dive under braking, no torque-steer under hard acceleration. Even if the AWD only works at some times, the vehicle can have a quite different feel to it.
Funny story from back in the day on the Murano forums...guy in snow country parks on a hill, left two wheels on the plowed pavement and right two wheels on the snow, puts the transmission in Park but doesn't set the e-brake, gets out and proceeds to watch his Murano roll down the hill!

Of course the two wheels on the snow were spinning backwards...
