Couple points. The transmission fluid and radiator hold completely separate fluids. The transmission has metal plumbing that runs through the radiator but the fluids do not mix in any way UNLESS the radiator is faulty. So if this guy thinks the transmission flush somehow made creamy stuff build-up in the radiator....then either your radiator is faulty or he doesn't understand basic mechanics. There really should not be any type of creamy stuff under the cap, particularly if it's NEW.
Have you check the transmission fluid to see how it looks?